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Material Safety Data Sheet

In accordance with 91/155/EEC

Printed on: 28 Nov. 2004

Revised on: June 01st, 2015

1.

NAME OF SUBSTANCE/PREPARATION AND COMPANY

Product details: Methylcyclopentadienyl Manganese Tricarbonyl, (62% MMT)

Trade name: TDS-1510 (62% MMT)

Manufacturer details:

TDS Chemical Corp., Ltd.

Office: Building No. 67, Unit 1225, No. 421, Hong-Cao Rd., Shanghai 200233, China

Plant: No.2 Waisha Industry Zone, Jiaojiang,Taizhou, Zhejiang 318000, China.

Tel: +86-21-6495 5601,

Fax: +86-21-6495 5601,

Email: tds@tdschem.com

Website: www.tdschem.com

Telephone: (+86) 21 6495 5601 (Mon. – Fri. 09.00 am – 18.00 pm)

Telephone: (+86) 186-0177 9000 (outside office hours)

FOR CHEMICAL EMERGENCY DURING TRANSPORTATION

International emergency responses 1.352.323.3500 call INFOTRAC collect. These numbers are used for leaks, fires and medical emergencies involving human and animals. 24 Hrs. per day, 7 days per week

For domestic within the USA pleas to use 1.800.535.5053.

2.

COMPOSITION / DETAILS OF CONSTITUENTS

Chemical name:

Methylcyclopentadienyl Manganese Tricarbonyl, (62% MMT)

CAS No.

12108-13-3

Molecular Weight

218.10

Chemical Formula

C9H7MnO3

3.

HAZARDS INDENTIFICATION

Emergency Overview

Very toxic by inalation, in contact with skin and if swallowed.

Potential Health Effects / Personal Protective Equipment

Eye

May cause eye irritation

Skin

May cause skin irritation. Toxic in contact with skin.

Ingestion

May cause irritation of the digestive tract. Poison by ingestion

Inhalation

May be fatal if inhaled. May cause respiratory tract irritation

Chronic

Not available

4.

FIRST AID MEASURES

Eye

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Skin

Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.

Ingestion

Get medical aid immediately. Wash mouth out with water

Inhalation

Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Notes to physician

Treat symptomatically and supportively

5.

FIRE FIGHTING MEASURES:

General Information

As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/MIOSH (approved or equivalent),and full protective gear. Will burn if involved in a fire

Extinguishing Media

Use water spray, dry chemical, chemical foam, carbon

dioxide, or chemical foam.

6.

ACCIDENTAL RELEASE MEASURES

Personal Precautions

When contacting with skin, wash immediately with soap solution.

Environmental Precautions

When it is leaked, wipe it off with a rag cloth or the like. Absorb with dry sand or earth and place in steel or plastic containers for disposal.

Methods for Cleaning Up

Minor leaks and residues should be hosed down with water and detergent.

7.

STABILITY AND REACTIVITY:

Chemical Stability

Stable under normal temperatures and pressures

Conditions to Avoid

Incompatible materials

Incompatibilities with Other Materials

Oxidizing agents, halogens

Hazardous Decomposition Products

Carbon monoxide, carbon dioxide, oxides of manganese

Hazardous Polymerization

Will not occur

8.

PHYSICAL AND CHEMICAL PROPERTIES

Color/dyed

Undyed

Pour Point (melt point)

-57.0

Freeze Point (Initial)

-30.0eddonomy Development Zone of Yungshan Rroup, Jiangxi, China

Specific Gravity @20/20℃

1.1442

Density (at @20℃ g/ml)

1.1421

C.O.T.E. 0.00099

N/A

Distillation

IBP

185

EBP

>212

Kinematic Viscosity at @20℃

1.967

Kinematic Viscosity at @0℃

3.186

Water Content

0.0050

Water and Sediment

0.00

Flash Point (closed @20℃

>70.0

Mn. Content

>15.1

Methylcyclopentadienyl Manganese

Tricarbonyl (Purity)

>62.0

Solvent Content

>38.0

V.P -0.2 MMHG (Vapor Lock Index)

<20

9.

EXPOSURE CONTROLS, PERSONAL PROTECTION

Engineering Controls

Use adequate ventilation to keep airborne concentrations low. Personal Protective Equipment

Eyes

Wear chemical goggles

Skin

Wear appropriate protective gloves to prevent skin exposure.

Clothing

Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Release Measure

General Information

Use proper personal protective equipment as indicated above

Spills/Leaks

Absorb spill with inert material (e.g.) vermiculite, sand or earth) then place in suitable container.

10.

HANDLING AND STORAGE:

Handling

Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.

Storage

Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container

11.

Toxicological information:

RTECS#:

CAS# 12108-13-3: OP1450000

LD50/LC50:

CAS# 12108-13-3: Draize test, rabbit, skin: 100 mg/24H Mild;Inhalation, mouse: LC50 = 58600 ug/m3/4H; Inhalation, rat: LC50 = 76mg/m3/4H; Oral, mouse: LD50 = 34 mg/kg; Oral, rabbit: LD50 = 95mg/kg; Oral, rat: LD50 = 8 mg/kg; Skin, rabbit: LD50 = 140 mg/kg; Skin, rat: LD50 = 665 mg/kg.

ACGIH, IARC, NIOSH, NTP, or OSHA

Not listed

12.

ECOLOGICAL INFORMATION:

Environmental Fate

Not available

Environmental Toxicity

No available

13.

DISPOSAL CONSIDERATIONS:

Dispose of in a manner consistent with federal, state, and local regulations.

14.

TRANSPORT INFORMATION:

IATA

Shipping Name

Metal carbonyls, liquid, n.o.s.

Class or Division

6.1

UN Number

3281

Packing Group

I

IMO

Shipping Name

Metal carbonyls, liquid, n.o.s.

Class or Division

6.1

UN Number

3281

Packing Group

I

RID/ADR

Shipping Name

Metal carbonyls, liquid, n.o.s.

Class or Division

6.1

UN Number

3281

Packing Group

I

Remarks: Please pay special attention to;

Pipe gasket or that the rubber equipments involving in using this product, we suggest you should use the rubber equipment made from Flu rubber, or made from nitrile-butadiene rubber (NBR) or use the Soft pipelines.

An Explosion-proof motors is necessary when pumping this products.

The user that when they pack or pour this product into a small bottle, please choose the small bottle made from PET material, but not use PVC material bottle.

15.

REGULATORY INFORMATION:

European Labeling in Accordance with EC Directives

Hazard Sybols

T+

Risk Phrases

R 24/25 Toxic in contact with skin and if swallowed. R 26 Very toxic by inhalation.

Safety Phrases

S 28A After contact with skin, wash immediately with plenty of water.

S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S 38 In case of insufficient ventilation, wear suitable respiratory equipment.

S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

WGK (Water Danger/Protection)

CAS# 12108-13-3:

No information available.

United Kingdom Occupational Exposure Limits

CAS# 12108-13-3:

OES-United Kingdom, TWA 0.1 mg/m3 TWA (as Mn)

CAS# 12108-13-3:

OES-United Kingdom, STEL 0.3 mg/m3 STEL (as Mn)

United Kingdom Maximum Exposure Limits

Canada

CAS# 12108-13-3 is listed on Canada's NDSL List.

CAS# 12108-13-3 is listed on Canada's Ingredient Disclosure List.

Exposure Limits

CAS# 12108-13-3: OEL-AUSTRALIA:TWA 0.2 mg/m3;Skin

OEL-BELGIUM:TWA 0.2 mg/m3;Skin

OEL-DENMARK:TWA 0.1ppm ( 0.2 mg/m3);Skin

OEL-FINLAND:TWA 0.2 mg/m3;STEL 0.6 mg/m3;Skin

OEL-FRANCE:TWA 0.2 mg/m3;Skin

OEL-SWITZERLAND:TWA 0.1 ppm (0.2 mg/m3);Skin JAN9

OEL-UNITED KINGDOM:TWA 9.2 mg/m3;STEL 0.6 mg/m3;Skin

OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV

OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

US FEDERAL

TSCA

CAS# 12108-13-3 is listed on the TSCA inventory.

16.

OTHER INFORMATION

This data is based on our current level of knowledge but does not constitute an assurance of product

properties and does not justify a contractual legal relationship. And the information above is believed to be

accurate and represents the best information currently available to TDS Chemical Corp., Ltd. However, we

make no warranty of merchantability or any other warranty, express or implied, with respect to such

information, and we assume no liability resulting from its use. Users should make their own investigations

to determine the suitability of the information for their particular purposes. In no way shall the company be

of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary

damages, howsoever arising, even if the company has been advised of the possibility of such damages.

The product is only for commercial processing / use.

Further information:

Manufacturer details:

TDS Chemical Corp., Ltd.

Office: Building No. 67, Unit 1225, No. 421, Hong-Cao Rd.,

Shanghai 200233, China

Plant: No.2 Waisha Industry Zone, Jiaojiang,Taizhou,

Zhejiang 318000, China.

Tel: +86-21-6495 5601,

Fax: +86-21-6495 5601,

Email: tds@tdschem.com

Website: www.tdschem.com

Department publishing:

This data sheet

Safety department

Contacts

Mr. Quangen Zhou

Telephone: (+86) 21 6495 5601 (Mon. – Fri. 09.00 am – 18.00 pm)

Telephone: (+86) 186-0177 9000 (outside office hours)

FOR CHEMICAL EMERGENCY DURING TRANSPORTATION

International emergency responses 1.352.323.3500 call INFOTRAC collect. These numbers are used for leaks, fires and medical emergencies involving human and animals. 24 Hrs. per day, 7 days per week

For domestic within the USA pleas to use 1.800.535.5053.