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Material Safety Data Sheet

In accordance with 91/155/EEC

Creation Date: 11 Dec. 2006

Revised on: June 01st, 2015

1.

NAME OF SUBSTANCE/PREPARATION AND COMPANY

Product details: Diesel pour point depressant (PPD-1818H)

Trade name: PPD-1818H

Manufacturer details:

TDS Chemical Corp., Ltd.

Office: Building No. 67, Unit 1225, No. 421, Hong-Cao Rd., Shanghai 200233, China

Plant: No.2 Waisha Industry Zone, Jiaojiang,Taizhou, Zhejiang 318000, China.

Tel: +86-21-6495 5601,

Fax: +86-21-6495 5601,

Email: tds@tdschem.com

Website: www.tdschem.com

Emergency telephone number to TDS Chemical Corp., Ltd.

Telephone: (+86) 21 6495 5601 (Mon. – Fri. 09.00 am – 18.00 pm)

Telephone: (+86) 186-0177 9000 (outside office hours)

FOR CHEMICAL EMERGENCY DURING TRANSPORTATION

International emergency responses 1.352.323.3500 call INFOTRAC collect. These numbers are used for leaks, fires and medical emergencies involving human and animals. 24 Hrs. per day, 7 days per week

For domestic within the USA pleas to use 1.800.535.5053.

PLEASE NOTE – SAFETY IS PRIORITY #1 ALL PERSONS ASSOCIATED WITH THE

HANDLING AND USE OF THIS MATERIAL MUST READ AND COMPLY WITH THIS MSDS.

2.

COMPOSITION / DETAILS OF CONSTITUENTS

Chemical characteristics:

Polymer based on ethylene in solvent

Hazardous ingredients:

Compound

Content

CAS No.

Ethylene-vinyl acetate copolymer

50% weight

24937-78-8

Solvent of open aromatic hydrocarbon

50% weight

1330-20-7

3.

POSSIBLE HAZARDS

Flammable, form into explosive compound when the vapor mixes with air; combustion & explosion on circumstances of visible fire, high temperature, or contacted with oxidant. React fiercely with oxidant. The vapor is lighter than air can spread to a rather wide distance at a low ground, and lead to back flash in circumstance of visible fire.

4.

FIRST AID MEASURES

General notes:

Immediately remove contaminated clothing

After inhaling:

If difficulties occur after vapor/ aerosol has been inhaled, fresh air, summon physician.

On skin contact:

Wash thoroughly with soap and water.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:

Immediately rinse mouse and then drink plenty of water, do not induce vomiting, summon physician.

Note to physician:

Treat according to symptoms (decontamination vital function), no known specific antidote. When inhaled

(e.g. during vomiting) risk of pulmonary edemas and/or aerosol (e.g.dexamethazone).

5.

FIRES FIGHTING MEASURES

Suitable extinguishing media:

Dry extinguishing media, foam, carbon dioxide (CO2), water spray.

Unsuitable extinguishing media for safety reasons:

Full water jet. The following can be given off in a fire gases/vapors

The degree of risk is governed by the burning substance and fire condition

Special protective equipment:

In case of fire, wear a self contained breathing apparatus.

Further information:

Contaminated extinguishing water must be disposed of in accordance with local regulation.

6.

MEASURES IN THE EVENT OF UNINTENTIONAL RELEASE

Personal precautions:

Hand protection:

Protective gloves (butyl rubber) or (nitrile rubber)

Eye protection:

Avoid breathing vapor aerosol

Environmental precautions:

Do not discharge product into nature water without pretreatment (biological treatment plant)

Methods for cleaning up:

Contain with absorbent material and dispose.

Environmental measures:

Prevent from spreading (e.g. by damming, using chemical binders). Contaminate to environment, and do not allow enter into environment.

Do not allow product to enter the sewerage system.

Cleaning/collection procedure:

Collect using a fluid-binding material (chemicals or oil binders) and dispose of in accordance with the local regulations (special waste). Chlorine bleaching solution (1 part to 3 parts water).

Detoxification agents are oxidation agents and must never be used dry or undiluted, or mixed together with other detoxification agents.

In case of leakage:

Evacuate personnel to safety area, and segregate enter in & out. The disposal personnel should take Positive Pressure Air Breathing Apparatus, wear protective suits. Use sand, stone or other inert materials to assimilate. Or Construct fence or dig big pit to bury, Use anti-explosion pump to carry to particular tanker container, recycling or send to disposal yard for disposing.

7.

HANDLING AND STORAGE

Handling:

Instructions on safe handling:

Ensure thorough ventilation of stores work areas.

Protection against fire and explosion.

Take precautionary measures against static discharges.

Don’t close to open fires and heat sources, avoid exposure to the sunlight.

Storage:

Protect against temperature of above 70℃.

Storage temperature: 20 - 50℃.

Shelf life time:

At least 2years

8.

EXPOSURE CONTROL AND PERSONAL PROTECTION

Additional information on the layout of technical plant, Components with workplace control parameters.

Is to be observed: additional information see MARK list

Personal protective equipment.

Respiratory protection:

Avoid breathing vapor / aerosol

Hand protection:

Protective gloves (butyl rubber) or (nitrile rubber).

Eye protection:

goggles

General safety and hygiene measures:

The usual precautions for the handling of chemical must be observed.

9.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance form

Light red Viscous-like Liquid, No undissolvable impurities

Odor

Aromatic odor

Open aromatic hydrocarbon

(Boiling range)

180 ~ 240

Heavy aromatic hydrocarbon

(Boiling range)

159 ~ 180

Freeze point (initial)

≤ 30.0

Flash point (closed)

≥ 60.0

Density @ 20 ℃

900 ~ 950 (0.896=water 1)

Kinematics viscosity

20~200 mm2s-1

Acid value/m KOH. g-1

≤ 7.0

Water-soluble

Insoluble water

Photo-stability

Stable under ordinary conditions

10.

STABILITY AND REACTIVITY

Hazardous reaction:

None provided product is correctly processed

Hazardous decomposition products:

None provided product is correctly processed.

11.

TOXICOLOGICAL INFORMATION

Acute toxicity:

The statements are based on properties of the individual components. LD50/oral/rat: > 2000 mg/kg

Primary skin irritation/rabbit:

Irritant

Primary mucous membrane irritation/rabbit:

non-irritant

Additional information

When inhaled (e.g. during vomiting) risk of pulmonary edemas and /or pneumonia.

12.

ECOLOGICAL INFORMATION

Elimination information:

The substance can be virtually eliminated from water in suitable effluent treatment. Plants by biodegradation stripping and mechanical separation.

Behavior and environmental fate:

Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations.

Ecotoxic effects:

The statements are based on the properties of the individual components. Toxicity to fish: LD50(96h): 1-10mg/l

Further ecological information:

Will not pollute the effluent provided it is processed correctly.

13.

DISPOSAL CONSIDERATION

Contaminated packaging:

Must be dumped or incinerated in accordance with local regulations. Dispose with sand or earth if leakage. Uncontaminated packs can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents.

14.

TRANSPORT DATA

Land transportation ADR/RID:

Category

3 substances

ICAO-Label

Flammable Viscous-like Liquid.

Substance no. (UN no.)

UN1993

Hazard label

Class 3

Packaging group

II

Description of substance

Diesel pour point depressant. (PPD-1818H)

Sea freight IMDG

Category

3 substances

EMS no.

Class 3

Marine label

Flammable Viscous-like Liquid.

Substance no. (UN no.)

UN1993

Hazard label

Class 3

Packaging group

II

Proper shipping name

Diesel pour point depressant (PPD-1818H)

Air freight ICAO/IATA;

Category

3 substances

UN/ID no.

UN1993

Packaging group

II

Proper shipping name

Diesel pour point depressant (PPD-1818H)

Remarks

Air craft cargo only.

15.

REGULATIONS

Labeling in accordance with EEC guidelines:

The product is classified in accordance with EC guidelines / Flammable Viscous-like Liquid substances

ordinance and must be labeled.

Indicating letter

H+

Description

Flammable Viscous-like Liquid

Contains

Mixed Hydrocarbons.

Risk categories

Class 3

May damage unborn babies

33

Risk of cumulative effects.

Safety categories

53

Avoid exposure, obtain special instructions before use.

45

Consult a doctor immediately in case of accidents or illness.

National regulations for Hydrocarbons:

To be completed by the importer in accordance with the valid regulations.

16.

OTHER INFORMATION

This data is based on our current level of knowledge but does not constitute an assurance of product

properties and does not justify a contractual legal relationship. And the information above is believed to be

accurate and represents the best information currently available to TDS Chemical Corp., Ltd. However, we

make no warranty of merchantability or any other warranty, express or implied, with respect to such

information, and we assume no liability resulting from its use. Users should make their own investigations

to determine the suitability of the information for their particular purposes. In no way shall the company be

of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary

damages, howsoever arising, even if the company has been advised of the possibility of such damages.

The product is only for commercial processing / use.

Further information:

TDS Chemical Corp., Ltd.

Office:

Building No. 67, Unit 1225, No. 421, Hong-Cao Rd.,

Shanghai 200233, China

Plant:

No.2 Waisha Industry Zone, Jiaojiang,Taizhou, Zhejiang 318000, China.

Tel: +86-21-6495 5601,

Fax: +86-21-6495 5601,

Email: tds@tdschem.com

Website: www.tdschem.com

Department publishing:

This data sheet

Safety department

Contacts

Mr.zhou

Emergency telephone number to TDS Chemical Corp., Ltd. Safety department;

Telephone: (+86) 21 6495 5601 (Mon. – Fri. 09.00 am – 18.00 pm)

Telephone: (+86) 186-0177 9000 (outside office hours)

FOR CHEMICAL EMERGENCY DURING TRANSPORTATION

International emergency responses 1.352.323.3500 call INFOTRAC collect. These numbers are used for leaks, fires and medical emergencies involving human and animals. 24 Hrs. per day, 7 days per week

For domestic within the USA pleas to use 1.800.535.5053.